Gases

One of the criteria that scientists use to assess the probability of the existence of life on other planets is the presence of a habitable atmosphere. Lucky for us, the Earth’s atmosphere is one in a million (if not billion), that’s why we’re able to live on what we call the blue planet.

An atmosphere is defined as the layers of gases that surround any planet in general. Here on Earth, the composition of our troposphere (lowermost layer of the atmosphere) is most suitable to support life. In this module, we will tackle the third state of matter, gases, and the laws governing their behavior.

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Table of Contents

The Concept of Ideal Gas

Let us do an experiment first before we discuss this topic.

Put your palm near your mouth, and with your mouth wide open, try to blow some air towards your palm. How does it feel? Does it feel hot or cold? Next, try to pout, and again, with your palm near your mouth, blow some air into it. How does it feel now? It feels colder, right?

This phenomenon is called the Joule-Thomson expansion; your breath feels cooler as it passes through a smaller exit because the air in your breath behaves like a real gas. If your breath behaves as an ideal gas, there will be no difference in the temperature of the gas between the two scenarios that we did.

For a gaseous system to become ideal, there are four conditions that must be satisfied first, and these are the following:

  1. The gas particles have negligible volume.
  2. The gas particles are equally sized and do not interact with neighboring gas particles.
  3. The gas moves in a random motion.
  4. Collisions between gas particles are perfectly elastic.

As you can see from these assumptions, it is almost impossible to have an ideal (or perfect) gas, right? That’s true, but we can “force” the gas to behave ideally under low-pressure and high-temperature conditions.

Low pressure means that the gas occupies a large volume, and high temperature provides high kinetic energy to gas molecules, which can minimize the interactive forces between gas molecules. Furthermore, the use of gases with low molar mass (such as H2 gas) can further promote ideal behavior. In this section, we will deal with equations that describe the properties of ideal gases.

Empirical Gas Laws

1. Boyle’s Law

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©FilipiKnow

When you were a child, did you also try to push the plunger of a needleless syringe while sealing the exit with your finger? Back then, my goal was to push the plunger all the way to the tip of the syringe, not knowing that there is air inside which prevents me from doing so.

Fast forward to my high school days, during my Chemistry class, I recalled this experiment of mine and realized, “AHA, it’s Boyle’s Law!”

Boyle’s law relates the pressure and volume of an ideal gas under constant temperature. It states that at a constant temperature, the pressure of a fixed amount of gas is inversely proportional to the volume of the gas.

If you also did the syringe experiment, try to recall that the plunger becomes harder to push as the tip of the plunger approaches the tip of the syringe. This is because pushing the syringe further decreases the volume occupied by the gas, which results in an increased pressure exerted by the gas towards the plunger.

Quite amazing, right? We didn’t know back then that at such a young age, we already demonstrated Boyle’s law!

Although we demonstrated it using a syringe, Robert Boyle, a British chemist and natural philosopher, demonstrated this phenomenon in the 17th century by using a bent glass tube and mercury. By virtue of this law, it can be said that for a given sample of gas under two different sets of conditions, the relationship between its pressure and volume before and after the change is given as

boyle's law

where P is the pressure, and V is the volume of the gas under the two different sets of conditions. Keep in mind that this formula is valid only under constant temperature, and as long as the amount of the gas does not change.

MNEMONIC: Boyle’s Law is the first of the numerous gas laws that you will encounter. To easily recall what parameter is constant in Boyle’s law, just remember BOYLET (Boyle’s Law, constant T!)

Sample Problem:

A sample of oxygen gas exerts a pressure of 2.50 atm in a 20.0 L container. What will be the new pressure it will exert if all of it will be transferred to a 16.0 L container at constant temperature? Assume that the gas behaves ideally.

Solution:

Initially, the volume occupied by the gas is 20 L and exerts a pressure of 2.50 atm. Since the temperature and the amount of gas are constant, and the gas was assumed to behave ideally, we can use Boyle’s law to solve the new pressure after it was transferred to a 16 L container.

boyle's law sample problem and solution

Therefore, the new pressure is 3.125 atm.

2. Charles’s and Gay-Lussac’s Law

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©FilipiKnow

After Robert Boyle successfully established the relationship between volume and pressure in gases, one question arose:

Why does the pressure-volume relationship hold true only at constant temperature?

This was answered in the early 19th century by the separate work of Jacques Alexandre Cesar Charles and Joseph Louis Gay-Lussac. Their studies showed that at constant pressure, there exists a linear relationship between temperature and the volume of gases. Meaning, a certain amount of gas expands when heated, and contracts when cooled. Their separate work led to the development of Charles’s and Gay-Lussac’s law or simply, Charles’s law, which states that the volume of a fixed amount of gas maintained at constant pressure is directly proportional to the absolute temperature of the gas.

The mathematical expression of Charles’ law will lead to the derived equation

charles' law

where V1 and T1 are the initial volume and temperature, while V2 and T2 are the final volume and temperature, respectively.

When working with temperatures in gas laws, make sure that the temperature is always on the Kelvin scale, as it was clearly stated in the law that the proportionality was associated with the absolute temperature of the gas. Use the formula below to convert temperatures in ℃ to Kelvin.

T (in K) = T (in ℃) + 273

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 This animation demonstrating Charles’s law by NASA’s Glenn Research Center is in the public domain.

This observation can be explained by the expansion of the gas. As the temperature increases, the kinetic energy of gas molecules increases, which causes the gas to exert more pressure against the container. However, since the pressure is constant, the increase in pressure applied by the gas is manifested as an increase in the volume occupied by the gas.

Now, what if we let the expanding gas exert more pressure on its container while keeping the volume occupied by the gas constant? Doing so will lead us to the alternative form of Charles’s law, which some references call the Gay-Lussac’s law or the Amonton’s law. This relates the pressure and temperature of a fixed amount of gas under constant volume conditions and is mathematically expressed as:

gay-lussac’s law

where P1 and T1 are the initial volume and pressure, while P2 and T2 are the final volume and pressure, respectively.

MNEMONICS: To avoid confusion on which property is constant, you can just remember CHARLEP (Charles’ Law, constant Pressure).

3. Avogadro’s Law

Now, what if at constant temperature and pressure, we add a certain amount of gas to the system? What do you think will happen?

Well, in this respect, let’s just say that ideal gases are like your clothes. When you have so many clothes that they don’t fit your wardrobe anymore, normally, you (although most probably, it will be your mother) transfer your clothes to a larger wardrobe, right?

The same is true for ideal gases. If you increase the amount of gas under constant temperature and pressure conditions, the tendency of the gas is to increase its volume. This is known as Avogadro’s law, named after Italian chemist Lorenzo Romano Amedeo Carlo Avogadro.

Avogadro’s law states that at constant temperature and pressure, the volume of a gas is directly proportional to the number of moles of gas present. The mathematical expression of Avogadro’s law will lead to the derived equation.

avogadro’s law

where V1 and n1 are the initial volume and number of moles, while V2 and n2 are the final volume and number of moles, respectively.

Sample Problem:

What amount of an ideal gas must be added to double the volume occupied by the same gas with an initial amount of 0.25 moles under constant temperature and pressure?

Solution:

Since the system is subjected to constant temperature and pressure, we can use Avogadro’s law to solve this problem. However, we are not given the initial volume. For such cases, we can use arbitrary volume.

We want to compute the amount of gas that needs to be added so that the volume will be doubled. Hence, if we arbitrarily select V1 = 1.0 L, then V2 = 2.0 L. We are given the n1, hence, we can already solve the problem.

avogadro's law sample problem with solution

Although we got 0.50 mol as the final answer, this number does not answer our question. We were asked what amount of the gas must be added to double the volume that the gas will occupy. Initially, there’s 0.25 mol of gas. To double the volume, the amount of the resulting gas should be 0.50 mol. Hence, we need to add 0.25 mol of the same gas to the system.

4. Combined Gas Law

So far, we have considered cases wherein two variables are always constant. However, there are cases wherein the volume, temperature, and pressure all change at the same time. In such cases, the combined gas law can be used.

The combined gas law was obtained by combining Boyle’s law, Charles’ law, and Amonton’s law. This law expresses the relationship between the volume, pressure, and absolute temperature of a fixed amount of gas. The mathematical expression of the combined gas law will lead to the derived equation shown below.

combined gas law

Sample Problem:

A fixed amount of an ideal gas is being compressed to half of its original volume. If initially, the gas exerts 1.5 atm at a temperature of 300 K, what would be the ratio of final temperature over the final volume after compression if the pressure becomes 2.0 atm?

Solution:

It was stated that only the amount of gas is constant. Hence, we should use the combined gas law.

Since the gas is being compressed to half of its initial volume, and there is no initial volume given, then we can assign arbitrary values. For simplicity, we let V1 = 2.0 L and V2 = 1.0 L. Furthermore, P1 = 1.5 atm, T1 = 300 K, and P2 = 2.0 atm.

Using the combined gas law:

combined gas law sample problem and solution

What we have so far is the ratio of the final volume over the final temperature. However, we are asked to determine the ratio of final temperature over the final volume. We can get this by getting the reciprocal of the equation above, which gives us

combined gas law sample problem and solution 2

Ideal Gas Equation

The ideal gas equation accounts for the behavior of all ideal gas. This equation relates the pressure, absolute temperature, volume, and amount of the gas. This means that if we know three out of four properties of the gas, then we can compute the missing property using the ideal gas equation.

The mathematical expression of the ideal gas expression is shown below:

PV = nRT

R is known as the universal gas constant, which is equal to 0.0821 L⦁atm/mol⦁K, or  8.314 J/mol⦁K

IMPORTANT NOTE: A mole of ideal gases, regardless of identity, occupies a molar volume of 22.414 L at 273.15 K (or 0 ℃) with a pressure of 1 atm. This temperature and pressure condition is known as the standard temperature and pressure (STP). Another benchmark condition is known as the standard ambient temperature and pressure (SATP). At SATP, the temperature is 298.15 K (or 25 ℃) and the pressure is 1 bar.

Sample Problem:

Write an expression that will allow us to determine the volume occupied by 0.67 mol SF6 (146 g/mol) at SATP if it behaves as an ideal gas.

Solution:

Obviously, we need to use the ideal gas equation to be able to address this problem. To easily visualize the problem, let us first list what is known to us.

  • R = 0.0821 L⦁atm/mol⦁K
  • n = 0.67 mol
  • T = 298.15 K
  • P = 1 bar

Remember that we are asked to write an expression that will enable us to solve the volume of the gas. Hence, the units of the given that we need to use should cancel each other out.

If we are to use R = 0.0821 L⦁atm/mol⦁K, this means that the unit of amount should be in mole, the unit of temperature should be in Kelvin (K), and the unit of pressure should be in atmosphere (atm). That being said, we need to convert 1 bar to atm first. We know that 1 atm = 1.01325 bar. Therefore:

ideal gas equation sample problem and solution 1

Then, from the ideal gas equation:

ideal gas equation sample problem and solution 2

References

Chang, R. (2010). Chemistry (10th ed.). New York City, USA: McGraw-Hill Companies, Inc.

Gay-Lussac’s Law. (2022). Retrieved 17 June 2022, from https://chem.libretexts.org/Bookshelves/Introductory_Chemistry/Book%3A_Introductory_Chemistry_(CK-12)/14%3A_The_Behavior_of_Gases/14.05%3A_Gay-Lussac’s_Law

Kotz, J. (2022). Chemistry and Chemical Reactivity. Stamford, CT: Cengage Learning.

Silberberg, M. (2006). Chemistry: The molecular nature of matter and change (4th ed.). New York City, USA: McGraw-Hill Companies, Inc.

Zumdahl, S., Zumdahl, S., & DeCoste, D. (2010). Chemistry (8th ed.). Belmont, California: Brooks Cole.

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John Bryan Rolloque

John Bryan Rolloque graduated cum laude at the University of the Philippines Los Baños in 2018 under the B.S. Agricultural Chemistry program. He taught courses in general chemistry, analytical chemistry, and organic chemistry at UPLB’s Institute of Chemistry, and has been serving as the Region IV coordinator for the Regional and National Chemistry Olympiad. Landing 8th place in the 2019 licensure exam for agriculturists, he is now taking up his master’s degree in plant physiology, also in UPLB.

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