No. Unemployed people (without a previous record of coverage or contribution) are not allowed to start paying contribution as a voluntary member just so they can qualify for UMID or SSS benefits.
Voluntary membership is only for SSS members who are previously employed, self-employed, OFW, or non-working spouse and currently unemployed. This means you have to belong to one of those membership categories before becoming a voluntary member later on.
Moreover, only the first contribution payments from the employed, self-employed, non-working spouse or OFW members are considered valid by the SSS.
Any first contribution paid as a voluntary member is invalid and will be refunded.
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